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Scientific paper - Original scientific paper
Transmission electron microscopy, x-ray diffraction and Raman scattering studies of nanophase TiO_2
Fizika A, 6 (1997), 2; 77-88. urn:nbn:hr:217:973082
Turković, Aleksandra; Tonejc, Anđelka; Popović, Stanko; Dubček, Pavo; Ivanda, Mile; Musić, Svetozar; Gotić, Marijan

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Turković, A., Tonejc, A., Popović, S., Dubček, P., Ivanda, M., Musić, S. & Gotić, M. (1997). Transmission electron microscopy, x-ray diffraction and Raman scattering studies of nanophase TiO_2. Fizika A, 6. (2), 77-88. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:973082

Turković, Aleksandra, et al. "Transmission electron microscopy, x-ray diffraction and Raman scattering studies of nanophase TiO_2." Fizika A, vol. 6, no. 2, 1997, pp. 77-88. https://urn.nsk.hr/urn:nbn:hr:217:973082

Turković, Aleksandra, Anđelka Tonejc, Stanko Popović, Pavo Dubček, Mile Ivanda, Svetozar Musić and Marijan Gotić. "Transmission electron microscopy, x-ray diffraction and Raman scattering studies of nanophase TiO_2." Fizika A 6, no. 2 (1997): 77-88. https://urn.nsk.hr/urn:nbn:hr:217:973082

Turković, A., et al. (1997) 'Transmission electron microscopy, x-ray diffraction and Raman scattering studies of nanophase TiO_2', Fizika A, 6(2), pp. 77-88. Available at: https://urn.nsk.hr/urn:nbn:hr:217:973082 (Accessed 14 December 2024)

Turković A, Tonejc A, Popović S, Dubček P, Ivanda M, Musić S, and sur.. Transmission electron microscopy, x-ray diffraction and Raman scattering studies of nanophase TiO_2. Fizika A [Internet]. 1997 [cited 2024 December 14];6(2):77-88. Available at: https://urn.nsk.hr/urn:nbn:hr:217:973082

A. Turković, et al., "Transmission electron microscopy, x-ray diffraction and Raman scattering studies of nanophase TiO_2", Fizika A, vol. 6, no. 2, pp. 77-88, 1997. [Online]. Available at: https://urn.nsk.hr/urn:nbn:hr:217:973082. [Accessed: 14 December 2024]

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Metadata
Title (english)Transmission electron microscopy, x-ray diffraction and Raman scattering studies of nanophase TiO_2
AuthorAleksandra Turković
AuthorAnđelka Tonejc
AuthorStanko Popović
AuthorPavo Dubček
AuthorMile Ivanda
AuthorSvetozar Musić
AuthorMarijan Gotić
Author's institutionUniversity of Zagreb
Faculty of Science
(Department of Physics)
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Physics
Abstract (english)
Dye-sensitized solar cells differ from conventional semiconductor devices in that they separate the function of light absorption from charge-carrier transport. The device is based on a 10-µm-thick optically transparent film of titanium dioxide (TiO_2) particles of a few nanometers in size, coated with a monolayer of charge-transfer dye to sensitize the film for light harvesting. In the present authors' review, the principal role of the TiO_2 photoanode is emphasized by a detailed presentation of its characterization by different experimental methods, while the photoelectric responses of the cells, a work which is still in progress, are indicated in the references cited. Hydrolysis of Ti(IV)-isopropoxide in isopropanol by the addition of water is a suitable chemical reaction for the production of nanosized TiO_2. The properties of nanosized TiO_2 can be modified by the hydrolysis catalyst, pH of the solution, temperature, presence of complexing ligand and the colloidal state of TiO_2 precursor. In the present work, the microstructural properties of nanosized TiO_2 were studied by HREM, ED, XRD, SAXS and Raman spectroscopy. HREM was used to determine both grain and pore sizes. Electron diffraction and X-ray diffraction provided evidence of nanocrystalline anatase and brookite phases. The grain sizes of the anatase and brookite phases changed from (5±1) to (12±3) nm with an increase of the treating temperature up to 773 K, as shown by XRD. An method of determining nanosized TiO_2 grain size based on low-frequency Raman scattering, is presented.
Languageenglish
Publication typeScientific paper - Original scientific paper
Publication statusPublished
Peer reviewPeer review
Publication versionPublished version
Journal titleFizika A
Numberingvol. 6, no. 2, pp. 77-88
p-ISSN1330-0008
URN:NBNurn:nbn:hr:217:973082
Publication1997
Document URLhttp://fizika.hfd.hr/fizika_a/av97/a6p077.htm
Type of resourceText
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2019-10-04 15:48:10