prikaz prve stranice dokumenta Supramolecular motifs and solvatomorphism within the compounds [M(bpy)_3]_2[NbO(C_2O_4)_3]Cl•nH_2O (M=Fe^2+, Co^2+, Ni^2+, Cu^2+ and Zn^2+; n=11, 12). Syntheses, structures and magnetic properties
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Scientific paper - Original scientific paper
Supramolecular motifs and solvatomorphism within the compounds [M(bpy)_3]_2[NbO(C_2O_4)_3]Cl•nH_2O (M=Fe^2+, Co^2+, Ni^2+, Cu^2+ and Zn^2+; n=11, 12). Syntheses, structures and magnetic properties
Dalton Transactions, 6 (2008); 742-754. https://doi.org/10.1039/B707937K
Jurić, Marijana; Perić, Berislav; Brničević, Nevenka; Planinić, Pavica; Pajić, Damir; Zadro, Krešo; Giester, Gerald; Kaitner, Branko

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Jurić, M., Perić, B., Brničević, N., Planinić, P., Pajić, D., Zadro, K. ... Kaitner, B. (2008). Supramolecular motifs and solvatomorphism within the compounds [M(bpy)_3]_2[NbO(C_2O_4)_3]Cl•nH_2O (M=Fe^2+, Co^2+, Ni^2+, Cu^2+ and Zn^2+; n=11, 12). Syntheses, structures and magnetic properties. Dalton Transactions, 6., 742-754. doi: 10.1039/B707937K

Jurić, Marijana, et al. "Supramolecular motifs and solvatomorphism within the compounds [M(bpy)_3]_2[NbO(C_2O_4)_3]Cl•nH_2O (M=Fe^2+, Co^2+, Ni^2+, Cu^2+ and Zn^2+; n=11, 12). Syntheses, structures and magnetic properties." Dalton Transactions, vol. 6, 2008, pp. 742-754. https://doi.org/10.1039/B707937K

Jurić, Marijana, Berislav Perić, Nevenka Brničević, Pavica Planinić, Damir Pajić, Krešo Zadro, Gerald Giester and Branko Kaitner. "Supramolecular motifs and solvatomorphism within the compounds [M(bpy)_3]_2[NbO(C_2O_4)_3]Cl•nH_2O (M=Fe^2+, Co^2+, Ni^2+, Cu^2+ and Zn^2+; n=11, 12). Syntheses, structures and magnetic properties." Dalton Transactions 6 (2008): 742-754. https://doi.org/10.1039/B707937K

Jurić, M., et al. (2008) 'Supramolecular motifs and solvatomorphism within the compounds [M(bpy)_3]_2[NbO(C_2O_4)_3]Cl•nH_2O (M=Fe^2+, Co^2+, Ni^2+, Cu^2+ and Zn^2+; n=11, 12). Syntheses, structures and magnetic properties', Dalton Transactions, 6, pp. 742-754. doi: 10.1039/B707937K

Jurić M, Perić B, Brničević N, Planinić P, Pajić D, Zadro K, and sur.. Supramolecular motifs and solvatomorphism within the compounds [M(bpy)_3]_2[NbO(C_2O_4)_3]Cl•nH_2O (M=Fe^2+, Co^2+, Ni^2+, Cu^2+ and Zn^2+; n=11, 12). Syntheses, structures and magnetic properties. Dalton Transactions [Internet]. 2008 [cited 2024 November 20];6:742-754. doi: 10.1039/B707937K

M. Jurić, et al., "Supramolecular motifs and solvatomorphism within the compounds [M(bpy)_3]_2[NbO(C_2O_4)_3]Cl•nH_2O (M=Fe^2+, Co^2+, Ni^2+, Cu^2+ and Zn^2+; n=11, 12). Syntheses, structures and magnetic properties", Dalton Transactions, vol. 6, pp. 742-754, 2008. [Online]. Available at: https://urn.nsk.hr/urn:nbn:hr:217:939574. [Accessed: 20 November 2024]

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Title (english)Supramolecular motifs and solvatomorphism within the compounds [M(bpy)_3]_2[NbO(C_2O_4)_3]Cl•nH_2O (M=Fe^2+, Co^2+, Ni^2+, Cu^2+ and Zn^2+; n=11, 12). Syntheses, structures and magnetic properties
AuthorMarijana Jurić
AuthorBerislav Perić
AuthorNevenka Brničević
AuthorPavica Planinić
AuthorDamir Pajić
AuthorKrešo Zadro
AuthorGerald Giester
AuthorBranko Kaitner
Author's institutionUniversity of Zagreb
Faculty of Science
(Department of Physics)
Author's institutionUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Physics
Abstract (english)
Solvatomorphism has been found between two series of complexes of the composition [M(bpy)_3]_2[NbO(C_2O_4)_3]Cl•nH_2O [M = Fe^2+(1, 2), Co^2+(3, 4), Ni^2+(5, 6), Cu^2+(7) and Zn^2+(8, 9); bpy=2,2'-bipyridine)], crystallizing in the monoclinic space group P2_1/c[3, 5, 8 (n=11)] or in the orthorhombic space group P2_12_12_1[2, 4, 6, 7 (n= 12)]. All the structures contain two symmetry independent [M(bpy)_3]^2+ cations, one [NbO(C_2O_4)_3]^3- anion, one Cl– anion, and crystal water molecules. The cations possess a trigonally distorted octahedral geometry, with an additional tetragonal distortion in 7. Analysis of crystal packing reveals a specific type of supramolecular contact comprising four bipyridine ligands from two neighbouring [M(bpy)_3]^2+ cations – quadruple aryl embrace (QAE) contact. The contact is realized by the alignment of two molecular two-fold rotation axes, preserving the parallel orientation of the molecular three-fold rotation axes. The resulting two-dimensional honeycomb lattices of [M(bpy)_3]^2+ cations are placed between the hydrogen bonding layers made of [NbO(C_2O_4)_3]^3– and Cl– anions and the majority of crystal water molecules. The temperature-dependent magnetic susceptibility measurements (1.8–300 K) show a significant orbital angular momentum contribution for 3 and 4 (high-spin Co^2+), the influence of zero-field splitting for 5 and 6 (Ni^2+) and a substantially paramagnetic Curie behaviour for the Cu^2+ compound (7).
Keywords (english)
Languageenglish
Publication typeScientific paper - Original scientific paper
Publication statusPublished
Peer reviewPeer review - international
Publication versionAccepted version
Journal titleDalton Transactions
Numberingvol. 6, pp. 742-754
p-ISSN1477-9226
e-ISSN1477-9234
DOIhttps://doi.org/10.1039/B707937K
URN:NBNurn:nbn:hr:217:939574
Publication2008
ProjectNumber: 098-0982904-2946
Title (croatian): Višenuklearni metalni sustavi: sinteza i svojstva
Leader: Berislav Perić
Jurisdiction: Croatia
Funding stream: ZP
ProjectNumber: 119-1191458-1017
Title (croatian): Nanomagneti
Leader: Krešo Zadro
Jurisdiction: Croatia
Funding stream: ZP
ProjectNumber: 119-1193079-3069
Title (croatian): Novi organski i koordinacijski spojevi - sinteza i suodnos struktura-svojstvo
Leader: Branko Kaitner
Jurisdiction: Croatia
Funding stream: ZP
Type of resourceText
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2019-10-18 19:38:24