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Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility
Materials, 14 (2021), 19; 5543. https://doi.org/10.3390/ma14195543
Burazer, Sanja; Molčanov, Krešimir; Šantić, Ana; Klaser, Teodoro; Wenger, Emmanuel; Pajić, Damir; Jagličić, Zvonko; Popović, Jasminka; Jurić, Marijana

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Burazer, S., Molčanov, K., Šantić, A., Klaser, T., Wenger, E., Pajić, D. ... Jurić, M. (2021). Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility. Materials, 14. (19). doi: 10.3390/ma14195543

Burazer, Sanja, et al. "Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility." Materials, vol. 14, br. 19, 2021. https://doi.org/10.3390/ma14195543

Burazer, Sanja, Krešimir Molčanov, Ana Šantić, Teodoro Klaser, Emmanuel Wenger, Damir Pajić, Zvonko Jagličić, Jasminka Popović i Marijana Jurić. "Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility." Materials 14, br. 19 (2021). https://doi.org/10.3390/ma14195543

Burazer, S., et al. (2021) 'Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility', Materials, 14(19). doi: 10.3390/ma14195543

Burazer S, Molčanov K, Šantić A, Klaser T, Wenger E, Pajić D, i sur.. Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility. Materials [Internet]. 24.09.2021. [pristupljeno 25.09.2024.];14(19). doi: 10.3390/ma14195543

S. Burazer, et al., "Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility", Materials, vol. 14, br. 19, Rujan 2021. [Online]. Dostupno na: https://urn.nsk.hr/urn:nbn:hr:217:080448. [Citirano: 25.09.2024.]

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Naslov (engleski)Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility
AutorSanja Burazer
AutorKrešimir Molčanov
AutorAna Šantić
AutorTeodoro Klaser
AutorEmmanuel Wenger
AutorDamir Pajić
AutorZvonko Jagličić
AutorJasminka Popović
AutorMarijana Jurić
Autorova ustanovaSveučilište u Zagrebu
Prirodoslovno-matematički fakultet
(Fizički odsjek)
Znanstveno / umjetničko
područje, polje i grana		PRIRODNE ZNANOSTI
Fizika
Sažetak (engleski)
A novel one-dimensional (1D) oxalate-bridged coordination polymer of iron(III), {[NH(CH3)(C2H5)2][FeCl2(C2O4)]}n (1), exhibits remarkable humidity-sensing properties and very high proton conductivity at room temperature (2.70 × 10−4 (Ω·cm)−1 at 298 K under 93% relative humidity), in addition to the independent antiferromagnetic spin chains of iron(III) ions bridged by oxalate groups (J = −7.58(9) cm−1). Moreover, the time-dependent measurements show that 1 could maintain a stable proton conductivity for at least 12 h. Charge transport and magnetic properties were investigated by impedance spectroscopy and magnetization measurements, respectively. Compound 1 consists of infinite anionic zig-zag chains [FeCl2(C2O4)]nn− and interposed diethylmethylammonium cations (C2H5)2(CH3)NH+, which act as hydrogen bond donors toward carbonyl oxygen atoms. Extraordinarily, the studied coordination polymer exhibits two reversible phase transitions: from the high-temperature phase HT to the mid-temperature phase MT at T ~213 K and from the mid-temperature phase MT to the low-temperature phase LT at T ~120 K, as revealed by in situ powder and single-crystal X-ray diffraction. All three polymorphs show large linear thermal expansion coefficients.
Ključne riječi (engleski)
Jezikengleski
Vrsta publikacijeZnanstveni rad - Izvorni znanstveni rad
Status objaveObjavljen
Vrsta recenzijeRecenziran - međunarodna recenzija
Verzija publikacijeObjavljena verzija rada (izdavačev PDF)
Naslov časopisaMaterials
Brojčani podacivol. 14, br. 19, 5543
e-ISSN1996-1944
DOIhttps://doi.org/10.3390/ma14195543
URN:NBNurn:nbn:hr:217:080448
Datum objave publikacije2021-09-24
ProjektŠifra: IP-2019-04-5742
Naziv (hrvatski): Topološka raznolikost oksalatnih spojeva: sinteza, svojstva i upotreba za okside
Naziv (engleski): Topological Versatility of Oxalate-Based Compounds: Synthesis, Properties and Oxide-Related Usage
Kratica: TOPOXAL-SYPROXID
Voditelj: Marijana Jurić
Pravna nadležnost: Hrvatska
Financijer: Hrvatska zaklada za znanost
Linija financiranja: Research Projects
URL dokumentahttps://www.mdpi.com/1996-1944/14/19/5543
Vrsta resursaTekst
Prava pristupaOtvoreni pristup
Uvjeti korištenjaIkona licence Imenovanje 4.0 međunarodna (CC BY 4.0)
Javna napomena© 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/). Received: 2 September 2021. Accepted: 22 September 2021. Published: 24 September 2021.
Datum i vrijeme pohrane2024-09-25 20:49:48