prikaz prve stranice dokumenta Pressure evolution of the electronic structure of non-centrosymmetric EuRhGe3
  Download
PDF 1.7 MB
Scientific paper - Original scientific paper
Pressure evolution of the electronic structure of non-centrosymmetric EuRhGe3
Electronic Structure, 3 (2021), 3; 034002. https://doi.org/10.1088/2516-1075/ac0c27
Utsumi, Yuki; Batistić, Ivo; Balédent, V.; Shieh, S. R.; Dhami, Naveen Singh; Bednarchuk, O.; Kaczorowski, D.; Ablett, J. M.; Rueff, J. P.

Cite this document

Utsumi, Y., Batistić, I., Balédent, V., Shieh, S. R., Dhami, N. S., Bednarchuk, O. ... Rueff, J. P. (2021). Pressure evolution of the electronic structure of non-centrosymmetric EuRhGe3. Electronic Structure, 3. (3). doi: 10.1088/2516-1075/ac0c27

Utsumi, Yuki, et al. "Pressure evolution of the electronic structure of non-centrosymmetric EuRhGe3." Electronic Structure, vol. 3, no. 3, 2021. https://doi.org/10.1088/2516-1075/ac0c27

Utsumi, Yuki, Ivo Batistić, V. Balédent, S. R. Shieh, Naveen Singh Dhami, O. Bednarchuk, D. Kaczorowski, J. M. Ablett and J. P. Rueff. "Pressure evolution of the electronic structure of non-centrosymmetric EuRhGe3." Electronic Structure 3, no. 3 (2021). https://doi.org/10.1088/2516-1075/ac0c27

Utsumi, Y., et al. (2021) 'Pressure evolution of the electronic structure of non-centrosymmetric EuRhGe3', Electronic Structure, 3(3). doi: 10.1088/2516-1075/ac0c27

Utsumi Y, Batistić I, Balédent V, Shieh SR, Dhami NS, Bednarchuk O, and sur.. Pressure evolution of the electronic structure of non-centrosymmetric EuRhGe3. Electronic Structure [Internet]. 2021 July 15 [cited 2024 October 07];3(3). doi: 10.1088/2516-1075/ac0c27

Y. Utsumi, et al., "Pressure evolution of the electronic structure of non-centrosymmetric EuRhGe3", Electronic Structure, vol. 3, no. 3, July 2021. [Online]. Available at: https://urn.nsk.hr/urn:nbn:hr:217:233579. [Accessed: 07 October 2024]

Please login to the repository to save this object to your list.
Metadata
Title (english)Pressure evolution of the electronic structure of non-centrosymmetric EuRhGe3
AuthorYuki Utsumi
AuthorIvo Batistić
AuthorV. Balédent
AuthorS. R. Shieh
AuthorNaveen Singh Dhami
AuthorO. Bednarchuk
AuthorD. Kaczorowski
AuthorJ. M. Ablett
AuthorJ. P. Rueff
Author's institutionUniversity of Zagreb
Faculty of Science
(Department of Physics)
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Physics
Abstract (english)
Among europium compounds, pressure induced valence transition and/or intermediate valence state is often observed. In such systems, applying several GPa of pressure can drive a Eu valence from divalent to almost trivalent. Non-centrosymmetric EuRhGe3 possesses magnetic Eu2+ ions and exhibits antiferromagnetic ordering ∼11 K at ambient pressure. Pressure resistant magnetic ordering and stable divalent Eu state have been reported in EuRhGe3 . Here we study the pressure evolution of Eu valence of EuRhGe3 by x-ray absorption spectroscopy using partial fluoresence yield method. Our study revealed a successive increase of Eu valence by applying pressure without a first order valence transition. The obtained Eu mean valence approaches ∼2.4 around 40 GPa at 300 K but not fully become trivalent. Pressure evolution of the electronic structure is also studied by density functional theoretical approach. Our theoretical analysis suggests that the increase of Eu valence obtained by Eu L3 spectra is caused by an increase of Eu 5d orbital occupation but that of Eu 4f stays almost 4f 7 . Possibly the magnetic moments of Eu 4f 7 persist through the measurement pressure range, at least up to ∼ 40 GPa.
Keywords (english)
Languageenglish
Publication typeScientific paper - Original scientific paper
Publication statusPublished
Peer reviewPeer review - international
Publication versionPublished version
Journal titleElectronic Structure
Numberingvol. 3, no. 3, 034002
e-ISSN2516-1075
DOIhttps://doi.org/10.1088/2516-1075/ac0c27
URN:NBNurn:nbn:hr:217:233579
Publication2021-07-15
ProjectNumber: IP-2016-06-7258
Title (croatian): Fizika mnogočestičnih sustava - iskorištavanje svijeta kompleksnosti
Acronym: COMPLEX_ORBIS
Leader: Osor-Slaven Barišić
Jurisdiction: Croatia
Funding stream: Research Projects
Document URLhttps://iopscience.iop.org/article/10.1088/2516-1075/ac0c27
Type of resourceText
Access conditionsOpen access
Terms of useLicence Attribution 4.0 International (CC BY 4.0) icon
Public note© 2021 The Author(s). Published by IOP Publishing Ltd. Original content from this work may be used under the terms of the Creative Commons Attribution 4.0 licence. Received 1 February 2021. Revised 2 June 2021. Accepted for publication 17 June 2021. Published 15 July 2021.
Created on2024-09-15 16:13:58